10.Jack Krauser(Resident Evil 4)
9.First Abomination Fight(Hulk:Ultimate Destruction)
8.Zant(Legend of Zelda:Twilight Princess)
7.Black Baron(Madworld)
6.Henry(No More Heroes)
5.Third Jeanne Fight(Bayonetta)
4.Hercules(God of War 3)
3.Third Vergil Fight(Devil May Cry 3)
2.Ryuji(No More Heroes 2)
1.Liquid Ocelot(Metal Gear Solid 4)
Those are my favorites